Unexpected epimerization at C₂ in the Horner–Wadsworth–Emmons reaction of chiral 2-substituted-4-oxopiperidines
2006
Etayo, Pablo | Badorrey, Ramón | Díaz-de-Villegas, María D. | Galvez, José A.
The observed epimerization at C₂ in the Horner–Wadsworth–Emmons (HWE) reaction of chiral 2-substituted-4-oxopiperidines has been investigated and, on the basis of the experimental results, a mechanism for this unexpected process has been proposed.
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