Palladium-Catalyzed Annulation of Internal Alkynes: Direct Access to π-Conjugated Ullazines
2016
Wan, Danyang | Li, Xiaoyu | Jiang, Ruyong | Feng, Boya | Lan, Jingbo | Wang, Ruilin | You, Jingsong
A palladium-catalyzed cyclization reaction of 1-(2,6-dibromophenyl)-1H-pyrroles with alkynes has been developed to construct various π-conjugated indolizino[6,5,4,3-ija]quinolones (ullazines) with a reactive functional group tolerance. As illustrative examples, three new ullazine-based sensitizers are synthesized, and the performance of these dyes is examined in DSSC devices, which demonstrates the potential of direct C–H functionalization in the construction of organic optoelectronic materials.
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