Sodium and potassium 3-sila-β-diketiminates show new coordination modes
2002
Farwell, James D. | Hitchcock, Peter B. | Lappert, M. F.
The reaction between the lithium 3-sila-β-diketiminate (1) and the appropriate MOBuᵗ yielded the crystalline sodium (2) or potassium (3) 3-sila-β-diketiminate in high yield; X-ray crystal data and NMR spectra show new coordination modes for the [N(R)C(Ar)Si(R)C(Ar)N(R)]⁻ ligand (R = SiMe₃, Ar = C₆H₃Me₂-2,6).
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