[3 + 3]-Cycloaddition of α-Diazocarbonyl Compounds and N-Tosylaziridines: Synthesis of Polysubstituted 2H-1,4-Oxazines through Synergetic Catalysis of AgOTf/Cu(OAc)₂
2019
Fang, Shangwen | Zhao, Yanwei | Li, Haiyan | Zheng, Yonggao | Lian, Pengcheng | Wan, Xiaobing
An impressive and new [3 + 3]-cycloaddition of α-diazocarbonyl compounds with N-tosylaziridines via synergetic catalysis of AgOTf and Cu(OAc)₂ has been well described, which offers efficient access to highly substituted 2H-1,4-oxazine derivatives. A variety of α-diazocarbonyl compounds and N-tosylaziridines were compatible substrates with convenient operations under mild reaction conditions.
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