Transition Metal Photoredox Catalysis of Radical Thiol-Ene Reactions
2013
Tyson, Elizabeth L. | Ament, Michael S. | Yoon, Tehshik P.
We describe the anti-Markovnikov hydrothiolation of olefins using visible-light-absorbing transition metal photocatalysts. The key thiyl radical intermediates are generated upon quenching of photoexcited Ru*(bpz)₃² with a variety of thiols. The adducts of a wide variety of olefins and thiols are formed in excellent yield (73–99%).
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