A triangulo palladium cluster consisting of μ³-capping silyl ligands
2010
Armbruster, Felix | Meyer, Jens | Baldes, Alexander | Burgos, Pascual Oña | Fernández, Ignacio | Breher, Frank
We report on the utility of multifunctional, κ¹Si:κ³S-coordinated tris(methimazolyl)silanide ligands [Si(mtᴹᵉ)₃]⁻ for the stabilisation of a triangulo palladium cluster [Pd₃{Si(mtᴹᵉ)₃}₂] (3) consisting of very unusual μ³-capping SiR₃ donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.
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