High-power positive electrode based on synergistic effect of N- and WO3 -decorated carbon felt for vanadium redox flow batteries
2018
Hosseini, Mir Ghasem | Mousavihashemi, Seyedabolfazl | Murcia-López, Sebastián | Flox, Cristina | Andreu, Teresa | Morante, J. R. (Joan Ramón)
Although Vanadium Redox Flow Batteries (VRFB) are suitable for grid-scale applications, their power-related cost must be reduced in order to boost the use of this technology in the market, allowing their widespread commercialization. One effective way to make the VRFB a competitive and viable solution could be through new strategies for improving the electrocatalytic activity of the electrodes with enhanced electrolyte/electrode interface characteristics. Herein, we report the synergistic effect demonstrated by N- and WO₃- decorated carbon-based positive electrode, named HTNW electrode, which demonstrates the feasibility of achieving: i) enhanced electrocatalytic activity, achieving large current density and high reversibility towards VO²⁺/VO₂⁺ couple (promotion of oxygen and electron transfer processes), ii) decrement of the electron-transfer resistance from 76.18 Ω to 13.00 Ω for the pristine electrode and HTNW electrodes, respectively; iii) 51% of the electrolyte utilization ratio at high rates (i.e. 200 mA cm⁻²) with 70% of energy efficiency; iv) increment of more than 50% of the power–peak in comparison with pristine electrode.
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