Revealing the Phase-Transition Dynamics and Mechanism in a Spinel Li₄Ti₅O₁₂ Anode Material through in Situ Electron Microscopy
2020
Wang, Longfei | Zhang, Zhi | Cheng, Yongfa | Zhang, Yanan | Liu, Weifeng | Su, Jun | Liu, Nishuang | Gao, Yihua
Spinel Li₄Ti₅O₁₂ is considered as a promising anode material for long-life lithium-ion batteries because of the negligible volumetric variation during the insertion and extraction of Li ions. Phase transition is an inevitable process during the migration of Li ions, and the transition process and mechanism need detailed investigation down to the atomic scale. In this study, we investigated the behavior and mechanism on the phase transition of Li₄Ti₅O₁₂ through in situ transmission electron microscopy (TEM). It has been found that the spinel-structured Li₄Ti₅O₁₂ was gradually transformed to a rock salt structure under electron beam irradiation. A sharp interface with an epitaxial relationship was observed between the transformed rock salt phase and the parent spinel phase. Furthermore, the heterostructure with different crystal structures of Li₄Ti₅O₁₂ has been precisely tailored with electron beam irradiation. Our detailed in situ TEM results and theoretical calculations led to unprecedented level on the understanding of phase-transition mechanism in Li₄Ti₅O₁₂. This study demonstrates a possible approach to precisely engineer the crystal structure of materials and to realize a well-designed heterostructure in electrode materials.
Show more [+] Less [-]AGROVOC Keywords
Bibliographic information
This bibliographic record has been provided by National Agricultural Library