Lewis acid–surfactant-combined catalyzed synthesis of 4-aminocyclopentenones from glycals in water
2013
Wang, Siming | William, Ronny | Georgina Estelle Seah, Kim Kui | Liu, Xue-Wei
4-Aminocyclopentenones were synthesized from readily available glycals and secondary anilines, with the aid of a Lewis acid–surfactant-combined catalyst. The reactions proceeded via a 4π conrotatory electrocyclization, affording the corresponding 4-aminocyclopentenones in good yields with excellent diastereoselectivities.
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