A non-singlet oxygen mediated reaction photoinduced by phenalenone, a universal reference for singlet oxygen sensitization
2014
Lorente, Carolina | Arzoumanian, Emmanuel | Castaño, Carolina | Oliveros, Esther | Thomas, Andrés H.
Photosensitized oxidations involve the generation of radicals (type I mechanism) and/or the production of singlet molecular oxygen (¹O₂) (type II mechanism). Phenalenone (PN) is one of the well-known type II photosensitizers and is widely used as a ¹O₂ reference sensitizer. In this work, we have studied the interaction of tryptophan (Trp) with the excited states of PN, the production of ¹O₂ in the presence of Trp, the formation of radicals and the kinetics of the photodegradation of Trp under different experimental conditions. In contrast to what is usually assumed, we have proven that PN is also able to act as a type I photosensitizer. Moreover, we have demonstrated that the predominant mechanism of the photosensitization of Trp by PN involves an electron transfer initiated-process.
Show more [+] Less [-]AGROVOC Keywords
Bibliographic information
This bibliographic record has been provided by National Agricultural Library