Bi(OAc)₃/chiral phosphoric acid catalyzed enantioselective allylation of isatins
2019
Wang, Jie | Zhang, Qingxia | Li, Yao | Liu, Xiangshuai | Li, Xin | Cheng, Jin-Pei
Herein, we disclosed an efficient protocol for the construction of chiral 3-allyl-3-hydroxyoxindoles via the enantioselective allylation reaction of isatins and allylboronates catalyzed by a simple binary acid Bi(OAc)₃/CPA system under mild conditions. The synthetic utility of this strategy has been demonstrated through the formal synthesis of ent-CPC-1.
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