Eliminating the need for independent counterions in the construction of metal–organic rotaxane frameworks (MORFs)
2009
Knight, Lisa K. | Vukotic, V Nicholas | Viljoen, Elizabeth | Caputo, Christopher B. | Loeb, Stephen J.
The combination of a disulfonated-dibenzo-24crown-8 ether wheel and a dicationic 1,2-bis(pyridinium)ethane axle yields a neutral [2]pseudorotaxane which in combination with neutral metallic units such as a Cu(ii)benzoate paddlewheel or Cu(i)Br unit yields one-dimensional coordination polymers (linear and bent) which are the first examples of charge neutral, metal–organic rotaxane frameworks.
Show more [+] Less [-]AGROVOC Keywords
Bibliographic information
This bibliographic record has been provided by National Agricultural Library