Cyclization reaction of N-allylbenzothioamide for direct construction of thiazole and thiazoline
2015
Zhou, Wei | Ni, Shengyang | Mei, Haibo | Han, Jianlin | Pan, Yi
A facile catalyst-free intramolecular cyclization reaction of N-allylbenzothioamide was reported. The reactions with the substrates bearing electron-withdrawing groups afforded thiazoles as products, while thiazolines formed from the reactions with substrates containing electron-donating groups as well as aliphatic substrate. This reaction provides a new access to 2,5-disubstituted thiazoles and thiazolines directly from readily available N-allylbenzothioamide.
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