Rhodium-Catalyzed Direct Ortho C–H Arylation Using Ketone as Directing Group with Boron Reagent
2017
Zhang, Bing | Wang, Huai-Wei | Kang, Yan-Shang | Zhang, Ping | Xu, Hua-Jin | Lu, Yi | Sun, Wei-Yin
A general method for selective ortho C–H arylation of ketone, with boron reagent enabled by rhodium complexes with excellent yields, is developed. The transformation is characterized by the use of air-stable Rh catalyst, high monoarylation selectivity, and excellent yields of most of the substrates.
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