Homocoupling of aryl Grignard reagents to form biaryls using ruthenium(III) complex, [RuCl(C₃S₅)(H₂O)(PPh₃)₂]
2012
Aparna, P.I. | Bhat, Badekai Ramachandra
Ruthenium(III) complex, [RuCl(C₃S₅)(H₂O)(PPh₃)₂] is an effective catalyst for the homocoupling of the aryl-Grignard reagents (ArMgX) to form biaryl derivatives. The catalytic methodology involves an in situ generation of the Grignard reagents. The method is simpler, economical and of great synthetic utility. The reaction will be environmental friendly due to the involvement of molecular oxygen as oxidant.
Show more [+] Less [-]AGROVOC Keywords
Bibliographic information
This bibliographic record has been provided by National Agricultural Library