Pd-Catalyzed C–H Fluorination with Nucleophilic Fluoride

McMurtrey, Kate B.; Racowski, Joy M.; Sanford, Melanie S.

Pd-Catalyzed C–H Fluorination with Nucleophilic Fluoride

2012

McMurtrey, Kate B. | Racowski, Joy M. | Sanford, Melanie S.

The palladium-catalyzed C–H fluorination of 8-methylquinoline derivatives with nucleophilic fluoride is reported. This transformation involves the use of AgF as the fluoride source in combination with a hypervalent iodine oxidant. Both the scope and mechanism of the reaction are discussed.

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AGROVOC Keywords

catalytic activity chemical reactions chemical structure fluorides iodine organic compounds oxidants palladium

Bibliographic information

Published in

Organic letters

Volume 14 Issue 16 Pagination 4094 - 4097 ISSN 1523-7052

Publisher

American Chemical Society

Other Subjects

Lewis bases

Language

English

License

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Type

Text; Journal Article

In AGRIS since: 2024-02-28

Format: MODS

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Links

DOI http://dx.doi.org/10.1021%2Fol301739f

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