Cobalt-catalyzed carboxylation of propargyl acetates with carbon dioxide
2014
Nogi, Keisuke | Fujihara, Tetsuaki | Terao, Jun | Tsuji, Yasushi
The cobalt-catalyzed carboxylation of propargyl acetates with CO₂ (1 atm) is described. The reaction proceeds at room temperature in the presence of Mn powder as a reducing reagent. Various propargyl acetates are converted to the corresponding carboxylic acids in good to high yields.
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