Stereoselective Synthesis of cis-2-Fluorocyclopropanecarboxylic Acid
2014
Shibue, Taku | Fukuda, Yasumichi
A rhodium-catalyzed cyclopropanation of 1-fluoro-1-(phenylsulfonyl)ethylene and diazo esters is described as an effective method for the stereoselective synthesis of cis-2-fluorocyclopropanecarboxylic acid. This process provides an example of the cyclopropanation of electron-deficient olefin and diazoacetates.
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