Palladium-Catalyzed Trifluoromethylthiolation of Aryl C–H Bonds
2014
Xu, Chunfa | Shen, Qilong
A method for monotrifluoromethylthiolation of arenes via palladium-catalyzed directed C–H bond activation was described. The reaction was compatible with a variety of functional groups. Initial mechanistic studies disclosed that the turnover limiting step of the catalytic cycle did not involve C–H activation.
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