Total Synthesis of (±)-Maoecrystal V
2012
Peng, Feng | Danishefsky, Samuel J.
The total synthesis of racemic maoecrystal V has been accomplished. Key steps include an intramolecular Diels–Alder cyclization to rapidly construct the core system from simple starting materials and the creation of the A–C ring trans-fusion through intramolecular delivery of a hydrogen to the hindered β-face of the ring system.
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