Ultrasound-promoted N-alkylation of imidazole. Catalysis by solid-base, alkali-metal doped carbons
2002
López-Pestaña, J. M. | Ávila-Rey, M. J. | Martín-Aranda, R. M.
The synthesis of N-substituted imidazoles via alkylation of imidazole with 1-bromobutane by sonochemical and thermally-activated reactions over two alkali-metal promoted carbons (Na⁺- and Cs⁺-Norit) as catalysts is reported. In this green, solvent free procedure, N-substituted imidazoles are produced exclusively in very high yields (>80%) when the Cs⁺-Norit carbon is employed under ultrasound activation. The basicity of the alkali metal cation increases the conversion and ultrasound activation affords a remarkable increase in the yields.
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