Air-Stable Chiral Single-Molecule Magnets with Record Anisotropy Barrier Exceeding 1800 K
2021
Zhu, Zhenhua | Zhao, Chen | Feng, Tingting | Liu, Xiaodong | Ying, Xu | Li, Xiao-Lei | Zhang, Yi-Quan | Tang, Jinkui
Design and synthesis of air-stable and easily tailored high-performance single-molecule magnets (SMMs) are of great significance toward the implementation of SMMs in molecular-based magneto-electronic devices. Here, by introducing electron-withdrawing fluorinated substituents on equatorial ligand, two chiral Dy(III) macrocyclic complexes, RRRR-Dy-D₆ₕF₁₂ (1) and SSSS-Dy-D₆ₕF₁₂ (2), with a record anisotropy barrier exceeding 1800 K and the longest relaxation time approaching 2500 s at 2.0 K for all known air-stable SMMs, were obtained. The nearly perfect axiality of the ground Kramers doublet (KD) enables the open hysteresis loops up to 20 K in the magnetically diluted sample. It is notable that they are structurally rigid with high thermal stability and the apical ligand can be tailored to carry proper surface-binding groups. This finding not only improves the magnetic properties for air-stable SMMs but also provides a new avenue for deposition of SMMs on surfaces.
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