An expedient osmium(vi)/K₃Fe(CN)₆-mediated selective oxidation of benzylic, allylic and propargylic alcohols
2014
Fernandes, Rodney A. | Bethi, Venkati
A chemoselective osmium(vi) catalyzed oxidation of benzylic, allylic and propargylic alcohols using K₃Fe(CN)₆ as a secondary oxidant is described. This protocol is operationally simple and exhibits excellent chemoselectivity favouring the oxidation of benzylic alcohols over the aliphatic alcohols. A larger scale reaction was also found to be compatible.
Show more [+] Less [-]AGROVOC Keywords
Bibliographic information
This bibliographic record has been provided by National Agricultural Library