Acid/Base-Co-catalyzed Formal Baeyer–Villiger Oxidation Reaction of Ketones: Using Molecular Oxygen as the Oxidant
2018
Liu, Chun-Hua | Wang, Zhuo | Xiao, Li-Yun | Mukadas, | Zhu, Dong-Sheng | Zhao, Yu-long
A novel acid/base-co-catalyzed formal Baeyer–Villiger oxidation of various ketones using O₂ as the sole oxidant under metal-free conditions has been developed for the first time. The reaction tolerates a wide range of ketones and anilines and provides a simple and efficient method for the construction of various amides and isoquinolin-1-ones from the reactions of ketones with anilines in a single step.
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