Electrochemical supercapacitor development based on electrodeposited nickel oxide film
2015
Navale, S. T. | Mali, V. V. | Pawar, S. A. | Mane, R. S. | Naushad, M. | Stadler, F. J. | Patil, V. B.
A nickel oxide (NiO) electrode has been synthesized electrochemically, which is envisaged for supercapacitor application. The structural, morphological, and phase-purity confirmation studies of NiO films were undertaken using X-ray diffraction, Fourier transform infrared spectroscopy (FTIR), field-emission scanning electron microscopy, and contact angle measurements. Films of NiO were amorphous in phase, as there were no reflecting planes in the X-ray diffraction pattern. The presence of characteristic bands in FTIR and X-ray photoelectron spectroscopy analysis corroborated the NiO structure. The NiO film surface was smooth with very fine elongated particles (∼70 nm) and hydrophilic in character (57°). The supercapacitive performance of an NiO electrode tested using cyclic voltammetry measurement in 0.5 M Na₂SO₄ electrolyte within the potential range of −1.2 to +1.2 V demonstrated a specific capacitance as high as 458 F g⁻¹ at 5 mV s⁻¹. The obtained specific energy, specific power and Coulomb efficiency of NiO electrode were 10.90 W h kg⁻¹, 0.89 kW kg⁻¹, and 98%, respectively.
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