Revisiting the reactive chemistry of FOX-7: cyclization of FOX-7 affords the fused-ring polynitro compounds
2019
Yan, Chao | Qi, Xiujuan | Wang, Kangcai | Jin, Yunhe | Cheng, Guangbin | Liu, Tianlin | Yang, Hongwei | Zhang, Qinghua
A novel fused-ring polynitro compound (5) and a cyclic compound featuring gem-dinitromethylene and nitroso groups (7) were synthesized from 1,1-diamino-2,2-dinitroethylene (FOX-7). Both compounds exhibit high density, decent thermal stability, high detonation performances, and low mechanical sensitivities. This newly developed derivatization strategy enriches the ever-expanding reactive chemistry of FOX-7.
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