Ligand-Controlled Para-Selective C–H Arylation of Monosubstituted Arenes
2015
Xu, Hui | Shang, Ming | Dai, Hui-Xiong | Yu, Jin-Quan
In a Pd-catalyzed double C–H activation reaction, a pyridine-type ligand is identified, for the first time, to enable a highly para-selective C–H arylation of monosubstituted arenes. Excellent para-selectivity is achieved with a variety of arenes containing alkyl, methoxyl, and halo substituents.
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