Synergistic formation of samarium oxide/graphene nanocomposite: A functional electrocatalyst for carbendazim detection
2022
Sakthi Priya, Thangavelu | Nataraj, Nandini | Chen, Tse-Wei | Chen, Shen-Ming | Kokulnathan, Thangavelu
Herein, an electrochemical sensor based on samarium oxide anchored, reduced graphene oxide (Sm₂O₃/RGO) nanocomposite was developed for the rapid detection of carbendazim (CBZ). Different characterization methods were infused to deeply examine the morphology, composition, and elemental state of Sm₂O₃/RGO nanocomposite. The Sm₂O₃/RGO modified electrode exhibits an excellent electro-catalytic performance toward CBZ detection with a peak potential of +1.04 V in phosphate buffer solution (pH 3.0), which is superior to the RGO–, Sm₂O₃– and bare– electrodes. This remarkable activity can be credited to the synergetic effect generated by the robust interaction between Sm₂O₃ and RGO, resulting in a well-enhanced electrochemical sensing ability. Impressively, the fabricated sensor shows improved electrochemical performance in terms of the wide working range, detection limit, and strong sensitivity. On a peculiar note, the electrochemical sensing performances of CBZ detection based on Sm₂O₃/RGO nanocomposite demonstrate an extraordinary behavior compared to the prior documented electro-catalyst. In addition, the fabricated Sm₂O₃/RGO sensor also displays good operational stability, reproducibility, and repeatability towards the detection of CBZ. Furthermore, it was successfully applied to the CBZ detection in food and environmental water samples with satisfactory recovery. In accordance with our research findings, the Sm₂O₃/RGO nanocomposite could be used as an electro-active material for effectual electrochemical sensing of food and environmental pollutants.
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