Nitric Oxide Adsorption in MIL-100(Al) MOF Studied by Solid-State NMR
2018
Khan, Arafat Hossain | Barth, Benjamin | Hartmann, Martin | Haase, Jürgen | Bertmer, Marko
Adsorption of nitric oxide (NO) in the metal–organic framework (MOF) MIL-100(Al) is studied by solid-state NMR. Owing to a modified synthesis, no extraframework benzenetricarboxylate is present on the cost of a small amount of extraframework Al(OH)₃ as evident from ²⁷Al, ¹H, as well as heteronuclear correlation spectra. Five-coordinated aluminum sites represent about 50% of the aluminum in a dehydrated sample, which remain open for adsorption. With increasing NO loading, a decrease of five-coordinated aluminum with a subsequent increase of six-coordinated aluminum site intensity is found. Additionally, ¹H spin–lattice relaxation time T₁ is decreasing with an increasing amount of NO, which also supports the NO interaction with the MOF because of the paramagnetism of NO. Fourier-transform infrared spectroscopy data further hint at Al–NO interactions.
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