Photocatalytic removal of organic pollutants in aqueous solution by Bi₄NbₓTa₍₁₋ ₓ ₎O₈I
2012
Hu, Xing-Yun | Fan, Jing | Zhang, Ke-Lei | Wang, Jian-Ji
In this work, Bi₄NbₓTa₍₁₋ ₓ ₎O₈I photocatalysts have been synthesized by solid state reaction method and characterized by powder X-ray diffraction, scanning electron microscope and UV–Vis near infrared diffuse reflectance spectroscopy. The photocatalytic activity of these photocatalysts was evaluated by the degradation of methyl orange (MO) in aqueous solutions under visible light, UV light and solar irradiation. The effects of catalyst dosage, initial pH and MO concentration on the removal efficiency were studied, and the photocatalytic reaction kinetics of MO degradation as well. The results indicated that Bi₄NbₓTa₍₁₋ ₓ ₎O₈I exhibited high photocatalytic activity for the removal of MO in aqueous solutions. For example, the removal efficiency of MO by Bi₄Nb₀.₁Ta₀.₉O₈I was as high as 92% within 12h visible light irradiation under the optimal conditions: initial MO concentration of 5–10mgL⁻¹, catalyst dosage of 6gL⁻¹ and natural pH (6–8), the MO molecules could be completely degradated by Bi₄Nb₀.₁Ta₀.₉O₈I within 40min under UV light irradiation, and the photodegradation efficiency reaches to 60% after 7h solar irradiation. Furthermore, the photocatalytic degradation of Bisphenol A (BPA) was also investigated under visible light irradiation. It is found that 99% BPA could be mineralized by Bi₄Nb₀.₁Ta₀.₉O₈I after 16h visible light irradiation. Through HPLC/MS, BOD, TOC, UV–Vis measurements, we determined possible degradation products of MO and BPA. The results indicated that MO was degradated into products which are easier to be biodegradable and innocuous treated, and BPA could be mineralized completely. Furthermore, the possibility for the photosensitization effect in the degradation process of MO under visible light irradiation has been excluded.
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