Water helicate (H₂O)₇, hosted by a diamondoid metal–organic framework
2009
Mir, Mohammad Hedayetullah | Wang, Li | Wong, Ming Wah | Vittal, Jagadese J.
A new form of water aggregate, viz., (H₂O)₇ helicate, has been trapped between the ClO₄⁻ anions in the channels of a diamondoid metal–organic framework (MOF) where a small change in the structure of the backbone of the MOF from 1,10-phenanthroline to a 2,2′-bipyridine ligand transforms the cyclic to an acyclic water helicate.
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