Combination of ring-opening polymerization and “click” chemistry towards functionalization of aliphatic polyesters
2005
Riva, Raphaël | Schmeits, Stéphanie | Stoffelbach, François | Jérôme, Christine | Jerome, Robert | Lecomte, Philippe
Azide pendent groups of aliphatic polyesters have been derivatized into tertiary amines, ammonium salts and poly(ethylene oxide) grafts. The experimental conditions have been optimized (organic solvent, 35 °C), such that the aliphatic polyesters are not degraded, including even poly(lactide) which is very sensitive to attack by weak nucleophiles.
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