Dissociation Pathways in the Cysteine Dication after Site-Selective Core Ionization
2014
Laksman, J. | Kooser, K. | Levola, H. | Itälä, E. | Ha, D. T. | Rachlew, E. | Kukk, E.
A photoelectron–ion–ion coincidence experiment has been carried out on the amino acid molecule cysteine after core-ionization of the O 1s, N 1s, C 1s, and S 2p orbitals. A number of different dissociation channels have been identified. Some of them show strong site-selective dependence that can be attributed to a combination of nuclear motion in the core-ionized state and Auger processes that populate different final electronic states in the dication.
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