In Situ Observation of Gas Adsorption onto ZIF-8 Using Terahertz Waves
2017
Tanno, Takenori | Watanabe, Yutaro | Umeno, Kyoko | Matsuoka, Atsushi | Matsumura, Hirotoshi | Odaka, Masafumi | Ogawa, Nobuaki
The adsorption behavior of energy-related gases onto ZIF-8 was investigated using terahertz waves. Comparison of the terahertz transmission spectra of ZIF-8 before and after exposure to the gases revealed that the 2 THz vibrational mode was involved in the gate-opening motion of organic linker molecules. The adsorption properties of each gas were detailed by monitoring the intensities of the 2 THz absorption peak.
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