Modification of Li₂MnSiO₄ cathode materials for lithium-ion batteries: a review
2017
Cheng, Qiaohuan | He, Wen | Zhang, Xudong | Li, Mei | Wang, Lianzhou
Diversified and extended application of lithium-ion batteries require the development of innovative electrode materials with excellent electrochemical performances, which, to a large extent, depends on the cathode materials. In recent years, Li₂MnSiO₄ has attracted widespread attention due to its high thermal stability, abundance, low-cost and environmentally friendliness. Some of the most attractive characteristics of Li₂MnSiO₄ are that it possesses the high theoretical capacity of 333 mA h g⁻¹ and is much easier to achieve the transformation of Mn²⁺/Mn³⁺ and Mn³⁺/Mn⁴⁺ within the voltage range of the electrolyte system currently used in Li-ion batteries compared with the other lithium transition metal orthosilicates. However, Li₂MnSiO₄ suffers from the intrinsic drawbacks of low electronic/ionic conductivity and capacity fading upon cycling, limiting its application in next-generation lithium-ion batteries. In this review, the recent efforts to improve the electrochemical performances of Li₂MnSiO₄ were introduced. In particular, we provided a critical overview of the effective modification methods related to the Li₂MnSiO₄ cathode materials. The synthesis, structure, morphologies and physicochemical (especially electrochemical) performances of these promising cathode materials have been discussed in detail. We anticipate that this review will shed light on the sustainable development of high-performance and low cost Li-ion batteries.
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