Total synthesis of carbocyclic nucleoside (+)-neplanocin A
2015
Jung, Young-Hoon | Kim, Seung In | Hong, Yeon Ju | Park, Sook Jin | Kang, Kyung Tae | Kim, So Yeon | Kim, In-su
Asymmetric total synthesis of (+)-neplanocin A was concisely achieved from readily available d-galactose via the regioselective and diastereoselective amination of carbocyclic polybenzyl ether using chlorosulfonyl isocyanate and intramolecular olefin metathesis using second-generation Grubbs catalyst.
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