peri-Interactions in Naphthalenes, 7 [1]. A Hetera-naphthalene as a Model Compound for 8-Dimethylaminonaphth- 1-yl Silicon and Phosphorus Compounds
2014
Schiemenz, Günter Paulus | Näther, Christian
In a 4-isopropyl-1-oxa-3-oxonia-2-borata-naphthalene the isopropyl group exhibits the same conformational phenomena as the Me₂N group in 8-dimethylamino-naphth-1-yl-silanes and related phosphorus compounds. Since the details can be fully rationalized on the basis of the steric situation and electronic factors are excluded, the common features cannot serve to infer dative interaction from nitrogen to silicon / phosphorus resulting in hypercoordination of the third period element atoms in the reference compounds.
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