Additive- and Metal-Free, Predictably 1,2- and 1,3-Regioselective, Photoinduced Dual C–H/C–X Borylation of Haloarenes
2016
Mfuh, Adelphe M. | Nguyen, Vu T. | Chhetri, Bhuwan | Burch, Jessica E. | Doyle, John D. | Nesterov, Vladimir N. | Arman, Hadi D. | Larionov, Oleg V.
We report herein a simple, additive- and metal-free, photoinduced, dual C–H/C–X borylation of chloro-, bromo-, and iodoarenes. The reaction produces 1,2- and 1,3-diborylarenes on gram scales under batch and continuous flow conditions. The regioselectivity of the dual C–H/C–X borylation is determined by the solvent and the substituents in the parent haloarenes.
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