Three-component aminoselenation of alkenes via visible-light enabled Fe-catalysis
2020
Huang, Binbin | Li, Yanan | Yang, Chao | Xia, Wujiong
A visible-light-enabled, iron-catalyzed three-component reaction for difunctionalization of alkenes with amines and diselenides has been developed, wherein a photo-excitable Fe-amine complex is proposed as the key intermediate. This ligand- and base-free transformation proceeds smoothly under air atmosphere at room temperature and features broad substrate scope.
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