Nitrogen-doped carbon nanofibers with effectively encapsulated GeO₂ nanocrystals for highly reversible lithium storage
2015
Mei, Lin | Mao, Minglei | Chou, Shulei | Liu, Huakun | Dou, Shixue | Ng, Dickon H. L. | Ma, Jianmin
Germanium dioxide is a promising high-capacity anode material for lithium-ion batteries, but it usually exhibits poor cycling stability due to its large volume change during the lithiation/delithiation process. In this paper, homogeneous dispersive GeO₂ nanocrystals encapsulated by nitrogen-doped carbon nanofibers (GeO₂-CNFs) were prepared by a facile electrospinning technology. The GeO₂-CNF anode material exhibited remarkable capability at a high rate and excellent cycling stability (1031 mA h g⁻¹ at 100 mA g⁻¹ after 200 cycles). The good electrochemical performance could be attributed to the fact that ultra-uniform CNFs act as a blocking layer and a buffer layer to effectively hold GeO₂ nanocrystals and facilitate the formation of a stable solid electrolyte interphase during Li⁺ intake/removal. The strategy is a simple and effective method which may be extended to other high-capacity anode materials with a large volume change and low electrical conductivity.
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