Z-Selective intramolecular Horner–Wadsworth–Emmons reaction for the synthesis of macrocyclic alkenes
2011
Ando, Kaori | Sato, Kaori
The Z-selective intramolecular Horner–Wadsworth–Emmons reaction of the substrates 7–12 (RO)₂P(O)CHR′CO₂Et (R′=(CH₂)ₙCHO) (R=Ph or o-tBuC₆H₄) gives the 13–18-membered cyclic alkenes selectively (up to Z:E=97:3) in good yields using NaH in THF under high dilution conditions.
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Bibliographic information
Publisher
Elsevier Ltd
Other Subjects
Alkenes
Language
English
Type
Journal Article; Text
2024-02-29
MODS
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