CO₂ capture enhancement in InOF-1 via the bottleneck effect of confined ethanol
2016
Peralta, Ricardo A. | Campos-Reales-Pineda, Alberto | Pfeiffer, Heriberto | Álvarez, J Raziel | Zárate, J Antonio | Balmaseda, Jorge | González-Zamora, Eduardo | Martínez, Ana | Martínez-Otero, Diego | Jancik, Vojtech | Ibarra, Ilich A.
CO₂ capture of InOF-1 was enhanced 3.6-fold, at 1 bar and 30 °C, by confining EtOH within its pores. Direct visualisation by single crystal X-ray diffraction revealed that EtOH divides InOF-1 channels in wide sections separated by “bottlenecks” caused by EtOH molecules bonded to the μ₂-OH functional groups of InOF-1.
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