Reversible C–C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation
2003
Ball, Lee-Jon | Dickie, Anthony P. | Mair, Francis S. | Middleton, David A. | Pritchard, Robin G.
Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C–C bond which ruptures upon dissolution in non-co-ordinating solvents.
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