Pt-Catalyzed Enantioselective Cycloisomerization for the Synthesis of Planar-Chiral Ferrocene Derivatives
2016
Shibata, Takanori | Uno, Ninna | Sasaki, Tomoya | Kanyiva, Kyalo Stephen
Enantioselective cycloisomerization of 2-ethynyl-1-ferrocenylbenzene derivatives proceeded by using a chiral cationic platinum catalyst at room temperature. The intramolecular reaction gave planar–chiral naphthalene- and anthracene-fused ferrocene derivatives with high to excellent ee.
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