Sulfate encapsulation in a metal-assisted capsule based on a mono-pyridylurea ligand
2011
Yang, Zaiwen | Wu, Biao | Huang, Xiaojuan | Liu, Yanyan | Li, Shaoguang | Xia, Yana | Jia, Chuandong | Yang, Xiao-Juan
A sulfate-encapsulating complex, [Cu¹L₆]·3[Cu²L₂(DMF)₄](SO₄)₄ (1, L = N-(1-naphthyl)-N′-(3-pyridyl)urea) is synthesized in which two C₃-clefts of the octahedral complexes interdigitate to form a cavity to encapsulate the sulfate ion by six urea groups.
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