Robust, Fire-Safe, Monomer-Recovery, Highly Malleable Thermosets from Renewable Bioresources
2018
Wang, Sheng | Ma, Songqi | Li, Qiong | Yuan, Wangchao | Wang, Binbo | Zhu, Jin
Conventional thermosets are built by nonrenewable fossil resources and are arduous to be reprocessed, recycled, and reshaped due to their permanent covalent cross-linking, and their flammability makes them unsafe during use. Here, for the first time, we synthesized a novel Schiff base precursor from abundant and renewable lignin derivative vanillin and produced malleable thermosets (Schiff base covalent adaptable networks (CANs)) combining high performance, super-rapid reprocessability, excellent monomer recovery, and arbitrary permanent shape changeability as well as outstanding fire resistance. The Schiff base CANs exhibited high glass transition temperatures of ∼178 °C, tensile strength of ∼69 MPa, tensile modulus of ∼1925 MPa, excellent flame retardancy with UL-94 V0 rating and V1 rating, and high LOI of ∼30%. Meanwhile, three Schiff base CANs showed high malleability with the activation energy of the bond exchange of 49–81 kJ mol–¹ and could be reprocessed in 2–10 min at 180 °C. These Schiff base CANs provide a prime example to foster the development of advanced thermosetting materials from renewable bioresources.
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