Synthesis of S-Aryl Phosphorothioates by Copper-Catalyzed Phosphorothiolation of Diaryliodonium and Arenediazonium Salts
2016
Zhang, Liangliang | Zhang, Pengbo | Li, Xueqin | Xu, Jian | Tang, Guo | Zhao, Yufen
Green methods for the synthesis of S-aryl phosphorothioates have been developed based on copper-catalyzed multicomponent reactions involving diaryliodonium/arenediazonium salts, elemental sulfur, and R₂P(O)H compounds. Most target products are obtained with these two methods in good to high yields at room temperature. These transformations allow the direct formation P–S and C–S bonds in one reaction.
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