Zirconium catalysed intermolecular hydroamination reactions of secondary amines with alkynes
2015
Sun, Qiu | Wang, Yaorong | Yuan, Dan | Yao, Yingming | Shen, Qi
An in situ generated cationic zirconium complex stabilized by an n-butylamine-bridged bis(phenolato) ligand has been developed to catalyse hydroamination reactions of secondary amines, which is the first example of group 4 metal based catalysts capable of mediating intermolecular hydroamination reactions of N-aryl/alkyl amines.
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