Generation of the CF₃ radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes
2011
Zhang, Cheng-Pan | Wang, Zong-Ling | Chen, Qing-Yun | Zhang, Chun-Tao | Gu, Yu-Cheng | Xiao, Ji-Chang
The CF₃ radical was generated from the reaction of S-(trifluoromethyl)diphenylsulfonium triflate with Na₂S₂O₄ or HOCH₂SO₂Na under suitable conditions without further reduction. Based on this, a method for the synthesis of α-trifluoromethylated ketones has been successfully developed.
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