Some remarks on asymmetric syntheses from recent studies
1990
Baba, N. (Okayama Univ. (Japan). Faculty of Agriculture)
Some asymmetric syntheses were presented here and discussed briefly including NADH model reactions, phase transfer-catalyzed asymmetric epoxidation, enantiotopic group-selective hydrolysis of a malonic anhydride with alkoxide anion, intramolecular acid-catalyzed lactonizations, catalytic asymmetric Diels-Alder synthesis, asymmetric aldol condensation, chiral homoallyl alcohol synthesis, asymmetric addition of diethylzinc to aldehyde, kinetic resolution of racemic hydroperoxides and binaphthol by lipase, and lipase-catalyzed enantiotopic group differentiation of 2-O-benzylglycerol and 2-alkylpropanediol
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